Free sugar is present only in fruits and vegetables while most carbohydrates are polysaccharides.
Added free sugar (particularly in carbonated beverages) is another story.
Polysaccharides can be degraded into mono saccharides and therefore absorbed only if specific enzymes are present. All non digestible polysaccharides reach the lower gut and can be fermented by gut microflora.
The speed of polysaccharide of degradation is of great importance:
Fructose, dextrose, inverted sugar, maltodextrins: